Description
Efnisyfirlit
- Half-title
- Title
- Copyright
- Contents
- Foreword
- Preface
- Acknowledgments
- Addendum for the English edition
- Units and physical constants
- 1 Introduction
- 1.1 The structure of matter
- 1.1.1 Length scales from cosmology to elementary particles
- 1.1.2 States of matter
- 1.1.3 Elementary constituents
- 1.1.4 The fundamental interactions
- 1.2 Classical and quantum physics
- 1.3 A bit of history
- 1.3.1 Black-body radiation
- 1.3.2 The photoelectric effect
- 1.4 Waves and particles: interference
- 1.4.1 The de Broglie hypothesis
- 1.4.2 Diffraction and interference of cold neutrons
- 1.4.3 Interpretation of the experiments
- 1.4.4 Heisenberg inequalities I
- 1.5 Energy levels
- 1.5.1 Energy levels in classical mechanics and classical models of the atom
- 1.5.2 The Bohr atom
- 1.5.3 Orders of magnitude in atomic physics
- 1.6 Exercises
- 1.6.1 Orders of magnitude
- 1.6.2 The black body
- 1.6.3 Heisenberg inequalities
- 1.6.4 Neutron diffraction by a crystal
- 1.6.5 Hydrogen-like atoms
- 1.6.6 The Mach–Zehnder interferometer
- 1.6.7 Neutron interferometry and gravity
- 1.6.8 Coherent and incoherent neutron scattering by a crystal
- 1.7 Further reading
- 2 The mathematics of quantum mechanics I: finite dimension
- 2.1 Hilbert spaces of finite dimension
- 2.2 Linear operators on H
- 2.2.1 Linear, Hermitian, unitary operators
- 2.2.2 Projection operators and Dirac notation
- 2.3 Spectral decomposition of Hermitian operators
- 2.3.1 Diagonalization of a Hermitian operator
- 2.3.2 Diagonalization of a 2×2 Hermitian matrix
- 2.3.3 Complete sets of compatible operators
- 2.3.4 Unitary operators and Hermitian operators
- 2.3.5 Operator-valued functions
- 2.4 Exercises
- 2.4.1 The scalar product and the norm
- 2.4.2 Commutators and traces
- 2.4.3 The determinant and the trace
- 2.4.4 A projector in R3
- 2.4.5 The projection theorem
- 2.4.6 Properties of projectors
- 2.4.7 The Gaussian integral
- 2.4.8 Commutators and a degenerate eigenvalue
- 2.4.9 Normal matrices
- 2.4.10 Positive matrices
- 2.4.11 Operator identities
- 2.4.12 A beam splitter
- 2.5 Further reading
- 3 Polarization: photons and spin-1/2 particles
- 3.1 The polarization of light and photon polarization
- 3.1.1 The polarization of an electromagnetic wave
- 3.1.2 The photon polarization
- 3.1.3 Quantum cryptography
- 3.2 Spin 1/2
- 3.2.1 Angular momentum and magnetic moment in classical physics
- 3.2.2 The Stern–Gerlach experiment and Stern–Gerlach filters
- 3.2.3 Spin states of arbitrary orientation
- 3.2.4 Rotation of spin 1/2
- 3.2.5 Dynamics and time evolution
- 3.3 Exercises
- 3.3.1 Decomposition and recombination of polarizations
- 3.3.2 Elliptical polarization
- 3.3.3 Rotation operator for the photon spin
- 3.3.4 Other solutions of (3.45)
- 3.3.5 Decomposition of a 2×2 matrix
- 3.3.6 Exponentials of Pauli matrices and rotation operators
- 3.3.7 The tensor Epsilonijk
- 3.3.8 A 2 rotation of spin 1/2
- 3.3.9 Neutron scattering by a crystal: spin-1/2 nuclei
- 3.4 Further reading
- 4 Postulates of quantum physics
- 4.1 State vectors and physical properties
- 4.1.1 The superposition principle
- 4.1.2 Physical properties and measurement
- 4.1.3 Heisenberg inequalities II
- 4.2 Time evolution
- 4.2.1 The evolution equation
- 4.2.2 The evolution operator
- 4.2.3 Stationary states
- 4.2.4 The temporal Heisenberg inequality
- 4.2.5 The Schrödinger and Heisenberg pictures
- 4.3 Approximations and modeling
- 4.4 Exercises
- 4.4.1 Dispersion and eigenvectors
- 4.4.2 The variational method
- 4.4.3 The Feynman–Hellmann theorem
- 4.4.4 Time evolution of a two-level system
- 4.4.5 Unstable states
- 4.4.6 The solar neutrino puzzle
- 4.4.7 The Schrödinger and Heisenberg pictures
- 4.4.8 The system of neutral K mesons
- 4.5 Further reading
- 5 Systems with a finite number of levels
- 5.1 Elementary quantum chemistry
- 5.1.1 The ethylene molecule
- 5.1.2 The benzene molecule
- 5.2 Nuclear magnetic resonance (NMR)
- 5.2.1 A spin 1/2 in a periodic magnetic field
- 5.2.2 Rabi oscillations
- 5.2.3 Principles of NMR and MRI
- 5.3 The ammonia molecule
- 5.3.1 The ammonia molecule as a two-level system
- 5.3.2 The molecule in an electric field: the ammonia maser
- 5.3.3 Off-resonance transitions
- 5.4 The two-level atom
- 5.5 Exercises
- 5.5.1 An orthonormal basis of eigenvectors
- 5.5.2 The electric dipole moment of formaldehyde
- 5.5.3 Butadiene
- 5.5.4 Eigenvectors of the Hamiltonian (5.47)
- 5.5.5 The hydrogen molecular ion H+2
- 5.5.6 The rotating-wave approximation in NMR
- 5.6 Further reading
- 6 Entangled states
- 6.1 The tensor product of two vector spaces
- 6.1.1 Definition and properties of the tensor product
- Postulate V
- 6.1.2 A system of two spins 1/2
- 6.2 The state operator (or density operator)
- 6.2.1 Definition and properties
- 6.2.2 The state operator for a two-level system
- 6.2.3 The reduced state operator
- 6.2.4 Time dependence of the state operator
- 6.2.5 General form of the postulates
- 6.3 Examples
- 6.3.1 The EPR argument
- 6.3.2 Bell inequalities
- 6.3.3 Interference and entangled states
- 6.3.4 Three-particle entangled states (GHZ states)
- 6.4 Applications
- 6.4.1 Measurement and decoherence
- 6.4.2 Quantum information
- 6.5 Exercises
- 6.5.1 Independence of the tensor product from the choice of basis
- 6.5.2 The tensor product of two 2×2 matrices
- 6.5.3 Properties of state operators
- 6.5.4 Fine structure and the Zeeman effect in positronium
- 6.5.5 Spin waves and magnons
- 6.5.6 Spin echo and level splitting in NMR
- 6.5.7 Calculation of E(a, b)
- 6.5.8 Bell inequalities involving photons
- 6.5.9 Two-photon interference
- 6.5.10 Interference of emission times
- 6.5.11 The Deutsch algorithm
- 6.6 Further reading
- 7 Mathematics of quantum mechanics II: infinite dimension
- 7.1 Hilbert spaces
- 7.1.1 Definitions
- 7.1.2 Realizations of separable spaces of infinite dimension
- 7.2 Linear operators on H
- 7.2.1 The domain and norm of an operator
- 7.2.2 Hermitian conjugation
- 7.3 Spectral decomposition
- 7.3.1 Hermitian operators
- 7.3.2 Unitary operators
- 7.4 Exercises
- 7.4.1 Spaces of infinite dimension
- 7.4.2 Spectrum of a Hermitian operator
- 7.4.3 Canonical commutation relations
- 7.4.4 Dilatation operators and the conformal transformation
- 7.5 Further reading
- 8 Symmetries in quantum physics
- 8.1 Transformation of a state in a symmetry operation
- 8.1.1 Invariance of probabilities in a symmetry operation
- 8.1.2 The Wigner theorem
- 8.2 Infinitesimal generators
- 8.2.1 Definitions
- 8.2.2 Conservation laws
- 8.2.3 Commutation relations of infinitesimal generators
- 8.3 Canonical commutation relations
- 8.3.1 Dimension d = 1
- 8.3.2 Explicit realization and von Neumann’s theorem
- 8.3.3 The parity operator
- 8.4 Galilean invariance
- 8.4.1 The Hamiltonian in dimension d = 1
- 8.4.2 The Hamiltonian in dimension d = 3
- 8.5 Exercises
- 8.5.1 Rotations
- 8.5.2 Rotations and SU(2)
- 8.5.3 Commutation relations between momentum and angular momentum
- 8.5.4 The Lie algebra of a continuous group
- 8.5.5 The Thomas–Reiche–Kuhn sum rule
- 8.5.6 The center of mass and the reduced mass
- 8.5.7 The Galilean transformation
- 8.6 Further reading
- 9 Wave mechanics
- 9.1 Diagonalization of X and P and wave functions
- 9.1.1 Diagonalization of X
- 9.1.2 Realization in…
- 9.1.3 Realization in…
- 9.1.4 Evolution of a free wave packet
- 9.2 The Schrödinger equation
- 9.2.1 The Hamiltonian of the Schrödinger equation
- 9.2.2 The probability density and the probability current density
- 9.3 Solution of the time-independent Schrödinger equation
- 9.3.1 Generalities
- 9.3.2 Reflection and transmission by a potential step
- The potential step: total reflection
- The potential step: reflection and transmission
- 9.3.3 The bound states of the square well
- 9.4 Potential scattering
- 9.4.1 The transmission matrix
- 9.4.2 The tunnel effect
- 9.4.3 The S matrix
- 9.5 The periodic potential
- 9.5.1 The Bloch theorem
- 9.5.2 Energy bands
- 9.6 Wave mechanics in dimension d = 3
- 9.6.1 Generalities
- 9.6.2 The phase space and level density
- 9.6.3 The Fermi Golden Rule
- 9.7 Exercises
- 9.7.1 The Heisenberg inequalities
- 9.7.2 Wave-packet spreading
- 9.7.3 A Gaussian wave packet
- 9.7.4 Heuristic estimates using the Heisenberg inequality
- 9.7.5 The Lennard–Jones potential for helium
- 9.7.6 Reflection delay
- 9.7.7 A delta-function potential
- 9.7.8 Transmission by a well
- 9.7.9 Energy levels of an infinite cubic well in dimension d = 3
- 9.7.10 The probability current in three dimensions
- 9.7.11 The level density
- 9.7.12 The Fermi Golden Rule
- 9.7.13 Study of the Stern–Gerlach experiment
- 9.7.14 The von Neumann model of measurement
- 9.7.15 The Galilean transformation
- 9.8 Further reading
- 10 Angular momentum
- 10.1 Diagonalization of J2 and Jz
- 10.2 Rotation matrices
- 10.3 Orbital angular momentum
- 10.3.1 The orbital angular momentum operator
- 10.3.2 Properties of the spherical harmonics
- 1. Basis on the unit sphere
- 2. Relation to the Legendre polynomials
- 3. Transformation under rotation
- 4. Parity of the spherical harmonics
- 10.4 Particle in a central potential
- 10.4.1 The radial wave equation
- 10.4.2 The hydrogen atom
- 10.5 Angular distributions in decays
- 10.5.1 Rotations by pi, parity, and reflection with respect to a plane
- 10.5.2 Dipole transitions
- 10.5.3 Two-body decays: the general case
- 10.6 Addition of two angular momenta
- 10.6.1 Addition of two spins 1/2
- 10.6.2 The general case: addition of two angular momenta J1 and J2
- 10.6.3 Composition of rotation matrices
- 10.6.4 The Wigner–Eckart theorem (scalar and vector operators)
- 10.7 Exercises
- 10.7.1 Properties of J
- 10.7.2 Rotation of angular momentum
- 10.7.3 Rotations (theta, phi)
- 10.7.4 The angular momenta…
- 10.7.5 Orbital angular momentum
- 10.7.6 Relation between the rotation matrices and the spherical harmonics
- 10.7.7 Independence of the energy from m
- 10.7.8 The spherical well
- 10.7.9 The hydrogen atom for…
- 10.7.10 Matrix elements of a potential
- 10.7.11 The radial equation in dimension d = 2
- 10.7.12 Symmetry property of the matrices d(j)
- 10.7.13 Light scattering
- 10.7.14 Measurement of the Lambda0 magnetic moment
- 10.7.15 Production and decay of the rho+ meson
- 10.7.16 Interaction of two dipoles
- 10.7.17 Sigma0 decay
- 10.7.18 Irreducible tensor operators
- 10.8 Further reading
- 11 The harmonic oscillator
- 11.1 The simple harmonic oscillator
- 11.1.1 Creation and annihilation operators
- 11.1.2 Diagonalization of the Hamiltonian
- 11.1.3 Wave functions of the harmonic oscillator
- 11.2 Coherent states
- 11.3 Introduction to quantized fields
- 11.3.1 Sound waves and phonons
- 11.3.2 Quantization of a scalar field in one dimension
- 11.3.3 Quantization of the electromagnetic field
- 11.3.4 Quantum fluctuations of the electromagnetic field
- 11.4 Motion in a magnetic field
- 11.4.1 Local gauge invariance
- 11.4.2 A uniform magnetic field: Landau levels
- 11.5 Exercises
- 11.5.1 Matrix elements of Q and P
- 11.5.2 Mathematical properties
- 11.5.3 Coherent states
- 11.5.4 Coupling to a classical force
- 11.5.5 Squeezed states
- 11.5.6 Zero-point energy of the Debye model
- 11.5.7 The scalar and vector potentials in Coulomb gauge
- 11.5.8 Commutation relations and Hamiltonian of the electromagnetic field
- 11.5.9 Quantization in a cavity
- 11.5.10 Current conservation in the presence of a magnetic field
- 11.5.11 Non-Abelian gauge transformations
- 11.5.12 The Casimir effect
- 11.5.13 Quantum computing with trapped ions
- 11.6 Further reading
- 12 Elementary scattering theory
- 12.1 The cross section and scattering amplitude
- 12.1.1 The differential and total cross sections
- 12.1.2 The scattering amplitude
- 12.2 Partial waves and phase shifts
- 12.2.1 The partial-wave expansion
- 12.2.2 Low-energy scattering
- 12.2.3 The effective potential
- 12.2.4 Low-energy neutron–proton scattering
- 12.3 Inelastic scattering
- 12.3.1 The optical theorem
- 12.3.2 The optical potential
- 12.4 Formal aspects
- 12.4.1 The integral equation of scattering
- 12.4.2 Scattering of a wave packet
- 12.5 Exercises
- 12.5.1 The Gamow peak
- 12.5.2 Low-energy neutron scattering by a hydrogen molecule
- 12.5.3 Analytic properties of the neutron–proton scattering amplitude
- 12.5.4 The Born approximation
- 12.5.5 Neutron optics
- 12.5.6 The cross section for neutrino absorption
- 12.6 Further reading
- 13 Identical particles
- 13.1 Bosons and fermions
- 13.1.1 Symmetry or antisymmetry of the state vector
- 13.1.2 Spin and statistics
- 13.2 The scattering of identical particles
- 13.3 Collective states
- 13.4 Exercises
- 13.4.1 The Tonos- particle and color
- 13.4.2 Parity of the pi meson
- 13.4.3 Spin-1/2 fermions in an infinite well
- 13.4.4 Positronium decay
- 13.4.5 Quantum statistics and beam splitters
- 13.5 Further reading
- 14 Atomic physics
- 14.1 Approximation methods
- 14.1.1 Generalities
- 14.1.2 Nondegenerate perturbation theory
- 14.1.3 Degenerate perturbation theory
- 14.1.4 The variational method
- 14.2 One-electron atoms
- 14.2.1 Energy levels in the absence of spin
- 14.2.2 The fine structure
- 14.2.3 The Zeeman effect
- 14.2.4 The hyperfine structure
- 14.3 Atomic interactions with an electromagnetic field
- 14.3.1 The semiclassical theory
- 14.3.2 The dipole approximation
- 14.3.3 The photoelectric effect
- 14.3.4 The quantized electromagnetic field: spontaneous emission
- 14.4 Laser cooling and trapping of atoms
- 14.4.1 The optical Bloch equations
- 14.4.2 Dissipative forces and reactive forces
- 14.4.3 Doppler cooling
- 14.4.4 A magneto-optical trap
- 14.5 The two-electron atom
- 14.5.1 The ground state of the helium atom
- 14.5.2 The excited states of the helium atom
- 14.6 Exercises
- 14.6.1 Second-order perturbation theory and van der Waals forces
- 14.6.2 Order-alpha2 corrections to the energy levels
- 14.6.3 Muonic atoms
- 14.6.4 Rydberg atoms
- 14.6.5 The diamagnetic term
- 14.6.6 Vacuum Rabi oscillations
- 14.6.7 Reactive forces
- 14.6.8 Radiative capture of neutrons by hydrogen
- 14.7 Further reading
- 15 Open quantum systems
- 15.1 Generalized measurements
- 15.1.1 Schmidt’s decomposition
- 15.1.2 Positive operator-valued measures
- 15.1.3 Example: a POVM with spins 1/2
- 15.2 Superoperators
- 15.2.1 Kraus decomposition
- 15.2.2 The depolarizing channel
- 15.2.3 The phase-damping channel
- 15.2.4 The amplitude-damping channel
- 15.3 Master equations: the Lindblad form
- 15.3.1 The Markovian approximation
- 15.3.2 The Lindblad equation
- 15.3.3 Example: the damped harmonic oscillator
- 15.4 Coupling to a thermal bath of oscillators
- 15.4.1 Exact evolution equations
- 15.4.2 The Markovian approximation
- 15.4.3 Relaxation of a two-level system
- 15.4.4 Quantum Brownian motion
- 15.4.5 Decoherence and Schrödinger’s cats
- 15.5 Exercises
- 15.5.1 POVM as projective measurement in a direct sum
- 15.5.2 Using a POVM to distinguish between states
- 15.5.3 A POVM on two arbitrary qubit states
- 15.5.4 Transposition is not completely positive
- 15.5.5 Phase and amplitude damping
- 15.5.6 Details of the proof of the master equation
- 15.5.7 Superposition of coherent states
- 15.5.8 Dissipation in a two-level system
- 15.5.9 Simple models of relaxation
- 15.5.10 Another choice for the spectral function J(omega)
- 15.5.11 The Fokker–Planck–Kramers equation for a Brownian particle
- 15.6 Further reading
- Appendix A The Wigner theorem and time reversal
- A.1 Proof of the theorem
- A.2 Time reversal
- Appendix B Measurement and decoherence
- B.1 An elementary model of measurement
- B.2 Ramsey fringes
- B.3 Interaction with a field inside the cavity
- B.4 Decoherence
- Appendix C The Wigner–Weisskopf method
- References
- Index
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