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• Cover
• Preface to the Eleventh Edition
• Text Figures: Quick Reference Guide
• Chapter 1: Safety First, Last, and Always
• Accidents Will Not Happen
• Disposing of Waste
• Safety Data Sheets
• Green Chemistry
• An iBag for Your iThing
• Exercises
• Chapter 2: Keeping a Notebook
• A Technique Experiment
• A Synthesis Experiment
• The Six Maybe Seven Elements in Your Experimental Write-up
• The Acid Test
• Notebook Mortal Sin
• Calculation of Percent Yield (Not Yeild!)
• Estimation Is Your Friend
• Notes From My Bench
• Exercises
• Chapter 3: Mining Your Own Data
• Google and the Wiki
• The Terphenyl Anomaly
• Exercises
• Chapter 4: Jointware
• Stoppers with Only One Number
• Another Episode of Love of Laboratory
• Hall of Blunders and Things Not Quite Right
• The O-Ring and Cap Branch Out
• Greasing the Joints
• Storing Stuff and Sticking Stoppers
• Corking a Vessel
• Chapter 5: Microscale Jointware
• Microscale: A Few Words
• Uh-Oh Rings
• The O-Ring Cap Seal
• The Comical Vial (That’s Conical!)
• The Microscale Drying Tube
• Gas Collection Apparatus
• Chapter 6: Other Interesting Equipment
• Funnels, and Beakers, and Flasks—Oh My!
• The Flexible Double-Ended Stainless Steel Spatula
• Chapter 7: Pipet Tips
• Pre-Preparing Pasteur Pipets
• Pipet Cutting
• Pipet Filtering—Liquids
• Pipet Filtering—Solids
• Chapter 8: Syringes, Needles, and Septa
• The Rubber Septum
• Chapter 9: Clean and Dry
• Drying Your Glassware When You Don’t Need To
• Drying Your Glassware When You Do Need To
• Chapter 10: Drying Agents
• Typical Drying Agents
• Using a Drying Agent
• Following Directions and Losing Product Anyway
• Drying Agents: Microscale
• Drying in Stages: The Capacity and Efficiency of Drying Agents
• Exercises
• Chapter 11: On Products
• Solid Product Problems
• Liquid Product Problems
• The Sample Vial
• Hold It! Don’t Touch That Vial
• Chapter 12: The Melting-Point Experiment
• Sample Preparation
• Melting-Point Hints
• The Mel-Temp Apparatus
• The SRS DigiMelt
• The Fisher-Johns Apparatus
• The Thomas-Hoover Apparatus
• Using the Thiele Tube
• Exercises
• Chapter 13: Recrystallization
• Finding a Good Solvent
• General Guidelines for a Recrystallization
• Gravity Filtration
• The Buchner Funnel and Filter Flask
• The Hirsch Funnel and Friends
• Activated Charcoal
• The Water Aspirator: A Vacuum Source
• The Water Trap
• Working with a Mixed-Solvent System—The Good Part
• A Mixed-Solvent System—The Bad Part
• Salting Out
• World-Famous Fan-Folded Fluted Paper
• Exercises
• Chapter 14: Recrystallization: Microscale
• Isolating the Crystals
• Craig Tube Filtration
• Centrifuging the Craig Tube
• Chapter 15: Extraction and Washing
• Never-Ever Land
• Starting an Extraction
• Dutch Uncle Advice
• The Separatory Funnel
• How to Extract and Wash What
• Exercises
• Chapter 16: Extraction and Washing: Microscale
• Mixing
• Separation: Removing the Bottom Layer (Fig. 16.1)
• Separation: Removing the Top Layer (Fig. 16.2)
• Separation: Removing Both Layers
• Chapter 17: Sources of Heat
• Boiling Stones
• The Steam Bath
• The Bunsen Burner
• The Heating Mantle
• Proportional Heaters and Stepless Controllers
• Exercise
• Chapter 18: Clamps and Clamping
• Clamping a Distillation Setup
• Clipping a Distillation Setup
• Chapter 19: Distillation
• Distillation Notes
• Class 1: Simple Distillation (Fig. 19.1)
• The Distillation Example
• The Distillation Mistake
• Class 2: Vacuum Distillation
• Class 3: Fractional Distillation
• Azeotropes
• Class 4: Steam Distillation
• Steam Distillation Notes
• Simulated Bulb-to-Bulb Distillation: Fakelrohr
• Exercises
• Chapter 20: Microscale Distillation
• Like the Big Guy
• Microscale Distillation II: The Hickman Still
• Chapter 21: The Rotary Evaporator
• Exercises
• Chapter 22: Reflux and Addition
• Standard Reflux
• A Dry Reflux
• Addition and Reflux
• Exercise
• Chapter 23: Reflux: Microscale
• Addition and Reflux: Microscale
• Chapter 24: Sublimation
• Chapter 25: Microscale Boiling Point
• Microscale Boiling Point
• Ultramicroscale Boiling Point
• Chapter 26: Chromatography
• Adsorbents
• Separation or Development
• The Eluatropic Series
• Chapter 27: Thin-Layer Chromatography: TLC
• We Don’t Make Our Own TLC Plates Any More, But…
• The Plate Spotter
• Spotting the Plates
• Developing a Plate
• Visualization
• Interpretation
• Multiple Spotting
• Cospotting
• Other TLC Problems
• Preparative TLC
• Exercises
• Chapter 28: Wet-Column Chromatography
• Preparing the Column
• Compounds on the Column
• Visualization and Collection
• Wet-Column Chromatography: Microscale
• Flash Chromatography
• Microscale Flash Chromatography
• Exercises
• Chapter 29: Refractometry
• The Abbé Refractometer
• Before Using the Abbé Refractometer: A Little Practice
• Using the Abbé Refractometer
• Refractometry Hints
• Chapter 30: Gas Chromatography
• The Mobile Phase: Gas
• GC Sample Preparation
• GC Sample Introduction
• Sample in the Column
• Sample at the Detector
• Electronic Interlude
• Sample on the Computer
• Parameters, Parameters
• Exercises
• Chapter 31: HP Liquid Chromatography
• The Mobile Phase: Liquid
• HPLC Sample Preparation
• HPLC Sample Introduction
• Sample in the Column
• Sample at the Detector
• Sample on the Computer
• Parameters, Parameters
• Exercises
• Chapter 32: Infrared Spectroscopy: (And a Bit Of UV-VIS, Too)
• Molecules as Balls on Springs
• AH, Quantum Mechanics
• The Dissonant Oscillator
• But Wait! There’s More
• More Complicated Molecules
• Correlation Tables to the Rescue
• Troughs and Reciprocal Centimeters
• Some Functional Group Analysis
• A Systematic Interpretation
• IR Sample Preparation
• Running the Spectrum
• Interpreting IR Spectra—Finishing Touches
• The Fourier Transform Infrared (FTIR)
• A Reflectance Attachment: Something to Think About
• And UV-VIS Too!
• Electrons Get to Jump
• Instrument Configuration
• Exercises
• Chapter 33: Nuclear Magnetic Resonance
• Nuclei Have Spin, Too
• The Magnetic Catch
• Everybody Line Up, Flip, and Relax
• A More Sensitive Census
• The Chemical Shift
• T for One and Two
• Be It Better Resolved…
• Incredibly Basic FT-NMR
• NMR Sample Preparation
• Some NMR Terms and Interpretations
• Exercises
• Index
• End User License Agreement