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• COVER
• TITLE PAGE
• COPYRIGHT
• PREFACE
• History
• PART 1: Thermodynamics
• CHAPTER 1: Zeroth Law of Thermodynamics and Equations of State
• 1.1 STATE OF A SYSTEM
• 1.2 THE ZEROTH LAW OF THERMODYNAMICS
• 1.3 THE IDEAL GAS TEMPERATURE SCALE
• 1.4 IDEAL GAS MIXTURES AND DALTON’S LAW
• 1.5 REAL GASES AND THE VIRIAL EQUATION
• 1.6 P−V¯−T SURFACE FOR A ONE‐COMPONENT SYSTEM
• 1.7 CRITICAL PHENOMENA
• 1.8 THE VAN DER WAALS EQUATION
• 1.9 DESCRIPTION OF THE STATE OF A SYSTEM WITHOUT CHEMICAL REACTIONS
• 1.10 PARTIAL MOLAR PROPERTIES
• 1.11 SPECIAL TOPIC: BAROMETRIC FORMULA
• 1.12 MATHEMATICAL TREATISE: PARTIAL DERIVATIVES
• NINE KEY IDEAS IN CHAPTER 1
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 2: First Law of Thermodynamics
• 2.1 WORK AND HEAT
• 2.2 FIRST LAW OF THERMODYNAMICS AND INTERNAL ENERGY
• 2.3 EXACT AND INEXACT DIFFERENTIALS
• 2.4 WORK OF COMPRESSION AND EXPANSION OF A GAS AT CONSTANT TEMPERATURE
• 2.5 VARIOUS KINDS OF WORK
• 2.6 CHANGE IN STATE AT CONSTANT VOLUME
• 2.7 ENTHALPY AND CHANGE OF STATE AT CONSTANT PRESSURE
• 2.8 HEAT CAPACITIES
• 2.9 JOULE-THOMSON EXPANSION
• 2.10 ADIABATIC PROCESSES WITH GASES
• 2.11 THERMOCHEMISTRY
• 2.12 ENTHALPY OF FORMATION
• 2.13 CALORIMETRY
• 2.14 SPECIAL TOPIC: DIFFERENTIAL SCANNING CALORIMETRY (DSC)
• TWELVE KEY IDEAS IN CHAPTER 2
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 3: Second and Third Laws of Thermodynamics
• 3.1 ENTROPY AS A STATE FUNCTION
• 3.2 THE SECOND LAW OF THERMODYNAMICS
• 3.3 ENTROPY CHANGES IN REVERSIBLE PROCESSES
• 3.4 ENTROPY CHANGES IN IRREVERSIBLE PROCESSES
• 3.5 ENTROPY OF MIXING IDEAL GASES
• 3.6 ENTROPY AND STATISTICAL PROBABILITY
• 3.7 CALORIMETRIC DETERMINATION OF ENTROPIES
• 3.8 THE THIRD LAW OF THERMODYNAMICS
• 3.9 SPECIAL TOPIC: HEAT ENGINES
• 3.10 SPECIAL TOPIC: CARATHEODORY PRINCIPLE AND THE SECOND LAW
• NINE KEY IDEAS IN CHAPTER 3
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTE
• CHAPTER 4: Fundamental Equations of Thermodynamics
• 4.1 FUNDAMENTAL EQUATION FOR THE INTERNAL ENERGY
• 4.2 DEFINITIONS OF ADDITIONAL THERMODYNAMIC POTENTIALS USING LEGENDRE TRANSFORMS
• 4.3 EFFECT OF TEMPERATURE ON THE GIBBS ENERGY
• 4.4 EFFECT OF PRESSURE ON THE GIBBS ENERGY
• 4.5 FUGACITY AND ACTIVITY
• 4.6 THE SIGNIFICANCE OF THE CHEMICAL POTENTIAL
• 4.7 ADDITIVITY OF PARTIAL MOLAR PROPERTIES WITH APPLICATIONS TO IDEAL GASES
• 4.8 GIBBS–DUHEM EQUATION
• 4.9 SPECIAL TOPIC: ADDITIONAL APPLICATIONS OF MAXWELL RELATIONS
• 4.10 MATHEMATICAL TREATISE: LEGENDRE TRANSFORMS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 5: Chemical Equilibrium
• 5.1 DERIVATION OF THE GENERAL EQUILIBRIUM EXPRESSION
• 5.2 EQUILIBRIUM CONSTANT EXPRESSIONS FOR GAS REACTIONS
• 5.3 DETERMINATION OF EQUILIBRIUM CONSTANTS
• 5.4 USE OF STANDARD GIBBS ENERGIES OF FORMATION TO CALCULATE EQUILIBRIUM CONSTANTS
• 5.5 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT
• 5.6 EFFECT OF PRESSURE, INITIAL COMPOSITION, AND INERT GASES ON THE EQUILIBRIUM COMPOSITION
• 5.7 EQUILIBRIUM CONSTANTS FOR GAS REACTIONS WRITTEN IN TERMS OF CONCENTRATIONS
• 5.8 HETEROGENEOUS REACTIONS
• 5.9 DEGREES OF FREEDOM AND THE PHASE RULE
• 5.10 SPECIAL TOPIC: ISOMER GROUP THERMODYNAMICS
• 5.11 SPECIAL TOPIC: CHEMICAL EQUATIONS AS MATRIX EQUATIONS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 6: Phase Equilibrium
• 6.1 PHASE DIAGRAMS OF ONE-COMPONENT SYSTEMS
• 6.2 THE CLAPEYRON EQUATION
• 6.3 THE CLAUSIUS–CLAPEYRON EQUATION
• 6.4 VAPOR–LIQUID EQUILIBRIUM OF BINARY LIQUID MIXTURES
• 6.5 VAPOR PRESSURE OF NONIDEAL MIXTURES AND HENRY’S LAW
• 6.6 ACTIVITY COEFFICIENTS
• 6.7 COLLIGATIVE PROPERTIES
• 6.8 TWO-COMPONENT SYSTEMS CONSISTING OF SOLID AND LIQUID PHASES
• 6.9 SPECIAL TOPIC: EFFECT OF SURFACE TENSION ON THE VAPOR PRESSURE
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTE
• CHAPTER 7: Electrochemical Equilibrium
• 7.1 COULOMB’S LAW, ELECTRIC FIELD, AND ELECTRIC POTENTIAL
• 7.2 EQUILIBRIA INVOLVING POTENTIAL DIFFERENCES
• 7.3 EQUATION FOR AN ELECTROCHEMICAL CELL
• 7.4 ACTIVITY OF ELECTROLYTES
• 7.5 DEBYE–HÜCKEL THEORY*
• 7.6 DETERMINATION OF STANDARD THERMODYNAMIC PROPERTIES OF IONS
• 7.7 STANDARD ELECTRODE POTENTIALS
• 7.8 DETERMINATION OF pH
• 7.9 SPECIAL TOPIC: FUEL CELLS
• 7.10 SPECIAL TOPIC: MEMBRANE POTENTIAL
• 7.11 SPECIAL TOPIC: GIBBS ENERGY OF SOLVATION
• ELEVEN KEY IDEAS IN CHAPTER 7
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 8: Thermodynamics of Biochemical Reactions
• 8.1 EXACT TREATMENT OF THE DISSOCIATION OF WEAK ACIDS
• 8.2 PRACTICAL CALCULATIONS WITH WEAK ACIDS
• 8.3 THERMODYNAMICS OF ENZYME‐CATALYZED REACTIONS
• 8.4 FUNDAMENTAL EQUATION OF THERMODYNAMICS FOR THE TRANSFORMED GIBBS ENERGY
• 8.5 CALCULATION OF STANDARD TRANSFORMED FORMATION PROPERTIES OF REACTANTS IN BIOCHEMICAL REACTIONS
• 8.6 COUPLING OF BIOCHEMICAL REACTIONS
• 8.7 BINDING OF OXYGEN BY MYOGLOBIN AND HEMOGLOBIN
• 8.8 PROTEIN DENATURATION
• 8.9 DNA DENATURATION
• 8.10 SPECIAL TOPIC: STATISTICAL EFFECTS IN POLYPROTIC ACIDS
• NINE KEY IDEAS IN CHAPTER 8
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• PART 2: Quantum Chemistry
• CHAPTER 9: Quantum Theory
• 9.1 CLASSICAL MECHANICS FAILED TO DESCRIBE EXPERIMENTS ON ATOMIC AND MOLECULAR PHENOMENA
• 9.2 THE HEISENBERG UNCERTAINTY PRINCIPLE
• 9.3 THE SCHRÖDINGER EQUATION
• 9.4 OPERATORS
• 9.5 EXPECTATION VALUES AND SUPERPOSITION
• 9.6 PARTICLE IN A ONE‐DIMENSIONAL BOX
• 9.7 PARTICLE IN A THREE‐DIMENSIONAL BOX
• 9.8 RELATION BETWEEN COMMUTABILITY AND PRECISION OF MEASUREMENT
• 9.9 CLASSICAL HARMONIC OSCILLATOR
• 9.10 QUANTUM MECHANICAL HARMONIC OSCILLATOR
• 9.11 THE RIGID ROTOR
• 9.12 ANGULAR MOMENTUM
• 9.13 POSTULATES OF QUANTUM MECHANICS
• 9.14 SPECIAL TOPIC: THE TIME‐DEPENDENT SCHRÖDINGER EQUATION
• 9.15 SPECIAL TOPIC: TUNNELING AND REFLECTION
• 9.16 SPECIAL TOPIC: BLACKBODY RADIATION
• 9.17 SPECIAL TOPIC: SUPERPOSITION OF VIBRATIONAL STATES AND WAVE PACKETS
• 9.18 SPECIAL TOPIC: QUANTUM DOTS
• 9.19 MATHEMATICAL TREATISE: INTEGRATION BY PARTS AND COMMON INTEGRALS USED IN QUANTUM MECHANICS
• ELEVEN KEY IDEAS IN CHAPTER 9
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 10: Atomic Structure
• 10.1 THE SCHRÖDINGER EQUATION FOR HYDROGENLIKE ATOMS
• 10.2 THE SPECTRUM OF HYDROGEN ATOMS
• 10.3 EIGENFUNCTIONS AND PROBABILITY DENSITIES FOR HYDROGENLIKE ATOMS
• 10.4 ORBITAL ANGULAR MOMENTUM OF THE HYDROGENLIKE ATOM
• 10.5 ELECTRON SPIN
• 10.6 VARIATIONAL METHOD
• 10.7 HELIUM ATOM
• 10.8 PAULI EXCLUSION PRINCIPLE
• 10.9 HARTREE–FOCK SELF‐CONSISTENT FIELD METHOD
• 10.10 THE PERIODIC TABLE AND THE AUFBAU PRINCIPLE
• 10.11 IONIZATION ENERGY AND ELECTRON AFFINITY
• 10.12 ANGULAR MOMENTUM OF MANY‐ELECTRON ATOMS
• 10.13 ATOMIC TERM SYMBOLS
• 10.14 SPECIAL TOPIC: ATOMIC SPECTRA AND SELECTION RULES
• 10.15 SPECIAL TOPIC: ATOMIC UNITS
• 10.16 SPECIAL TOPIC: ANGULAR MOMENTUM OPERATORS
• 10.17 SPECIAL TOPIC: PERTURBATION THEORY
• TWELVE KEY IDEAS IN CHAPTER 10
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 11: Molecular Electronic Structure
• 11.1 THE BORN–OPPENHEIMER APPROXIMATION
• 11.2 THE HYDROGEN MOLECULE ION
• 11.3 CALCULATION OF THE ENERGY OF THE HYDROGEN MOLECULE ION
• 11.4 MOLECULAR ORBITAL DESCRIPTION OF THE HYDROGEN MOLECULE
• 11.5 ELECTRON CONFIGURATIONS OF HOMONUCLEAR DIATOMIC MOLECULES
• 11.6 ELECTRONIC STRUCTURE OF POLYATOMIC MOLECULES: VALENCE BOND METHOD
• 11.7 HÜCKEL MOLECULAR ORBITAL THEORY
• 11.8 DIPOLE MOMENTS AND IONIC BONDING
• 11.9 INTERMOLECULAR FORCES
• 11.10 SPECIAL TOPICS: HYDROGEN BONDS, HYBRID ORBITALS, AND BAND THEORY OF SOLIDS
• 11.11 SPECIAL TOPIC: ELECTRONEGATIVITY
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 12: Symmetry
• 12.1 SYMMETRY ELEMENTS AND SYMMETRY OPERATIONS
• 12.2 THE ROTATION OPERATION AND THE SYMMETRY AXIS
• 12.3 THE REFLECTION OPERATION AND THE SYMMETRY PLANE
• 12.4 THE INVERSION OPERATION AND THE CENTER OF SYMMETRY
• 12.5 ROTATION‐REFLECTION AND THE IMPROPER AXIS
• 12.6 IDENTIFICATION OF POINT GROUPS OF MOLECULES
• 12.7 WHAT SYMMETRY TELLS US ABOUT DIPOLE MOMENTS AND OPTICAL ACTIVITY
• 12.8 SPECIAL TOPIC: MATRIX REPRESENTATIONS
• 12.9 SPECIAL TOPIC: CHARACTER TABLES
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTE
• CHAPTER 13: Rotational and Vibrational Spectroscopy
• 13.1 THE BASIC IDEAS OF SPECTROSCOPY
• 13.2 EINSTEIN COEFFICIENTS AND SELECTION RULES
• 13.3 SCHRÖDINGER EQUATION FOR NUCLEAR MOTION
• 13.4 ROTATIONAL SPECTRA OF DIATOMIC MOLECULES
• 13.5 ROTATIONAL SPECTRA OF POLYATOMIC MOLECULES
• 13.6 VIBRATIONAL SPECTRA OF DIATOMIC MOLECULES
• 13.7 VIBRATION–ROTATION SPECTRA OF DIATOMIC MOLECULES
• 13.8 VIBRATIONAL SPECTRA OF POLYATOMIC MOLECULES
• 13.9 RAMAN SPECTRA
• 13.10 SPECIAL TOPIC: FOURIER TRANSFORM INFRARED SPECTROSCOPY
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• CHAPTER 14: Electronic Spectroscopy of Molecules
• 14.1 ELECTRONIC ENERGY LEVELS AND SELECTION RULES
• 14.2 ELECTRONIC ABSORPTION SPECTRA OF DIATOMIC MOLECULES AND THE FRANCK–CONDON PRINCIPLE
• 14.3 DETERMINATION OF DISSOCIATION ENERGIES
• 14.4 SPECTROPHOTOMETERS AND THE BEER–LAMBERT LAW
• 14.5 OSCILLATOR STRENGTH
• 14.6 ELECTRONIC SPECTRA OF POLYATOMIC MOLECULES
• 14.7 CONJUGATED MOLECULES: FREE‐ELECTRON MODEL
• 14.8 FLUORESCENCE AND PHOSPHORESCENCE
• 14.9 LASERS
• 14.10 PHOTOELECTRON SPECTROSCOPY
• 14.12 SPECIAL TOPIC: OPTICAL SPECTROSCOPIC CHARACTERIZATION OF BIOPOLYMER STRUCTURE (Contribution of Timothy A. Keiderling)
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 15: Magnetic Resonance Spectroscopy
• 15.1 NUCLEAR MAGNETISM AND NUCLEAR MAGNETIC RESONANCE
• 15.2 ENERGY LEVELS IN NUCLEAR MAGNETIC RESONANCE
• 15.3 FOURIER TRANSFORM NMR SPECTROMETER
• 15.4 THE CHEMICAL SHIFT
• 15.5 INTERNUCLEAR SPIN–SPIN COUPLING
• 15.6 SPIN–SPIN SPLITTING IN AX AND AB SYSTEMS
• 15.7 NUCLEAR MAGNETIC RELAXATION
• 15.8 TWO‐DIMENSIONAL NMR
• 15.9 ELECTRON SPIN RESONANCE
• 15.10 SPECIAL TOPIC: FOURIER TRANSFORMS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• Theoretical
• COMPUTER PROBLEMS
• NOTE
• CHAPTER 16: Statistical Mechanics
• 16.1 THE BOLTZMANN DISTRIBUTION
• 16.2 SINGLE‐MOLECULE PARTITION FUNCTION FOR AN IDEAL GAS
• 16.3 TRANSLATIONAL CONTRIBUTIONS TO THE THERMODYNAMIC PROPERTIES OF IDEAL GASES
• 16.4 VIBRATIONAL CONTRIBUTIONS TO THE THERMODYNAMIC PROPERTIES OF IDEAL GASES
• 16.5 ROTATIONAL CONTRIBUTIONS TO THE THERMODYNAMIC PROPERTIES OF IDEAL GASES
• 16.6 ELECTRONIC CONTRIBUTIONS TO THE THERMODYNAMIC PROPERTIES OF IDEAL GASES
• 16.7 THERMODYNAMIC PROPERTIES OF IDEAL GASES
• 16.8 DIRECT CALCULATION OF EQUILIBRIUM CONSTANTS FOR REACTIONS OF IDEAL GASES
• 16.9 EQUIPARTITION
• 16.10 ENSEMBLES
• 16.11 NONIDEAL GASES
• 16.12 HEAT CAPACITIES OF SOLIDS
• 16.13 SPECIAL TOPIC: FLUCTUATIONS OF THERMODYNAMIC QUANTITIES
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• Theoretical
• COMPUTER PROBLEMS
• NOTES
• PART 3: Kinetics
• CHAPTER 17: Kinetic Theory of Gases
• 17.1 PROBABILITY DENSITY FOR MOLECULAR SPEEDS OF GAS MOLECULES
• 17.2 VELOCITY DISTRIBUTION IN ONE DIRECTION
• 17.3 MAXWELL DISTRIBUTION OF SPEEDS
• 17.4 TYPES OF AVERAGE SPEEDS
• 17.5 PRESSURE OF AN IDEAL GAS
• 17.6 COLLISIONS WITH A SURFACE AND EFFUSION
• 17.7 COLLISIONS OF HARD‐SPHERE MOLECULES
• 17.8 EFFECTS OF MOLECULAR INTERACTIONS ON COLLISIONS
• 17.9 SPECIAL TOPIC: TRANSPORT PHENOMENA IN GASES
• 17.10 SPECIAL TOPIC: CALCULATION OF TRANSPORT COEFFICIENTS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 18: Experimental Kinetics and Gas Reactions
• 18.1 RATE OF REACTION
• 18.2 ORDER OF REACTION
• 18.3 REVERSIBLE FIRST‐ORDER REACTIONS
• 18.4 CONSECUTIVE FIRST‐ORDER REACTIONS
• 18.5 MICROSCOPIC REVERSIBILITY AND DETAILED BALANCE*
• 18.6 EFFECT OF TEMPERATURE
• 18.7 MECHANISMS OF CHEMICAL REACTIONS
• 18.8 RELATION BETWEEN RATE CONSTANTS FOR THE FORWARD AND BACKWARD REACTIONS
• 18.9 BIMOLECULAR REACTIONS
• 18.10 UNIMOLECULAR AND TRIMOLECULAR REACTIONS
• 18.11 UNBRANCHED CHAIN REACTIONS
• 18.12 BRANCHED CHAIN REACTIONS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 19: Chemical Dynamics and Photochemistry
• 19.1 SIMPLE COLLISION THEORY OF BIMOLECULAR REACTIONS
• 19.2 POTENTIAL ENERGY SURFACES
• 19.3 THEORETICAL CALCULATION OF A RATE CONSTANT
• 19.4 TRANSITION‐STATE THEORY
• 19.5 MOLECULAR BEAM EXPERIMENTS
• 19.6 PRINCIPLES OF PHOTOCHEMISTRY
• 19.7 RATES OF INTRAMOLECULAR PROCESSES AND INTERMOLECULAR ENERGY TRANSFER
• 19.8 PHOTOCHEMICAL REACTIONS AND THEIR QUANTUM YIELDS
• 19.9 THE OZONE LAYER IN THE STRATOSPHERE
• 19.10 FEMTOSECOND TRANSITION‐STATE SPECTROSCOPY* †
• 19.11 SPECIAL TOPIC: APPLICATIONS OF PHOTOCHEMISTRY
• 19.12 SPECIAL TOPIC: FLUORESCENCE RESONANCE ENERGY TRANSFER (FRET)
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 20: Kinetics in the Liquid Phase
• 20.1 VISCOSITY OF A LIQUID
• 20.2 DIFFUSION
• 20.3 MOBILITY OF AN ION
• 20.4 ENCOUNTER PAIRS AND SOLVENT CAGE
• 20.5 DIFFUSION‐CONTROLLED REACTIONS IN LIQUIDS
• 20.6 RELAXATION TIME FOR A ONE‐STEP REACTION
• 20.7 ACID AND BASE CATALYSIS
• 20.8 PRIMARY KINETIC SALT EFFECT
• 20.9 RATES OF ELECTRON TRANSFER REACTIONS
• 20.10 ENZYME CATALYSIS
• 20.11 OSCILLATING CHEMICAL REACTIONS
• 20.12 SPECIAL TOPIC: THE KINETIC MODEL FOR ELECTRON TRANSFER REACTIONS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• PART 4: Macroscopic and Microscopic Structures
• CHAPTER 21: Macromolecules
• 21.1 SIZE AND SHAPE OF MACROMOLECULES
• 21.2 OSMOTIC PRESSURE OF POLYMER SOLUTIONS
• 21.3 SPATIAL CONFIGURATION OF POLYMER CHAINS
• 21.4 MOLAR MASS DISTRIBUTIONS OF STEP‐GROWTH POLYMERS
• 21.5 DETERMINATION OF MOLAR MASSES USING VISCOSITY, SEDIMENTATION, AND LIGHT SCATTERING
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 22: Electric and Magnetic Properties of Molecules
• 22.1 POLARIZATION OF A DIELECTRIC
• 22.2 POLARIZABILITY OF A DIELECTRIC
• 22.3 ORIENTATION POLARIZATION OF A DIELECTRIC
• 22.4 REFRACTIVE INDEX
• 22.5 MAGNETIZATION
• 22.6 TYPES OF MAGNETIC MATERIALS
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 23: Solid‐State Chemistry
• 23.1 CLASSIFICATION OF CRYSTAL STRUCTURES
• 23.2 DESIGNATION OF CRYSTAL PLANES
• 23.3 DIFFRACTION METHODS
• 23.4 CUBIC LATTICES
• 23.5 ION RADII AND ATOM RADII
• 23.6 SCATTERING OF X‐RAYS FROM A UNIT CELL
• 23.7 BINDING FORCES AND PACKING IN CRYSTALS
• 23.8 STRUCTURE OF LIQUIDS*
• 23.9 LIQUID CRYSTALS
• 23.10 THEORETICAL TREATMENT OF THE ELECTRON DISTRIBUTION IN SOLIDS
• 23.11 SPECIAL TOPIC: SUPERCONDUCTIVITY
• 23.12 SPECIAL TOPIC: QUANTUM CONFINED SEMICONDUCTOR STRUCTURES
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• NOTES
• CHAPTER 24: Surface Dynamics
• 24.1 PHYSISORPTION AND CHEMISORPTION
• 24.2 LANGMUIR ADSORPTION ISOTHERM
• 24.3 USE OF ADSORPTION MEASUREMENTS TO DETERMINE SURFACE AREA
• 24.4 LOW‐ENERGY ELECTRON DIFFRACTION (LEED)
• 24.5 ELECTRON EMISSION FROM SURFACES
• 24.6 SCANNING TUNNELING MICROSCOPY (STM) AND ATOMIC FORCE MICROSCOPY (AFM)
• 24.7 THEORY OF SURFACE REACTIONS
• 24.8 HETEROGENEOUS CATALYSIS
• 24.9 SPECIAL TOPIC: SURFACE RECONSTRUCTION
• QUESTIONS ON CONCEPTS AND IDEAS
• REFERENCES
• EXERCISES
• PROBLEMS
• COMPUTER PROBLEMS
• APPENDICES
• APPENDIX A: Physical Quantities and Units
• APPENDIX B: Values of Physical Constants
• APPENDIX C: Tables of Physical Chemical Data
• APPENDIX D: Mathematical Relations
• D.1 LOGARITHMS AND EXPONENTIALS
• D.2 SERIES
• D.3 CALCULUS
• D.4 SPHERICAL COORDINATES
• D.5 LEGENDRE TRANSFORMS
• D.6 DETERMINANTS
• D.7 VECTORS
• D.8 MATRICES*
• D.9 COMPLEX NUMBERS
• D.10 MATHEMATICAL CALCULATIONS WITH PERSONAL COMPUTERS
• NOTE
• APPENDIX E: Greek Alphabet
• APPENDIX F: Useful Information on the Web
• APPENDIX G: Symbols for Physical Quantities and Their SI Units*
• APPENDIX H: Answers to Exercises
• INDEX
• END USER LICENSE AGREEMENT