Principles of Ecotoxicology

Höfundur C.H. Walker; R.M. Sibly; D.B. Peakall

Útgefandi Taylor & Francis

Snið ePub

Print ISBN 9781138423848

Útgáfa 4

Útgáfuár 2012

17.890 kr.

Description

Efnisyfirlit

  • Cover
  • Half-Title Page
  • Title Page
  • Copyright Page
  • Dedication
  • Table of Contents
  • Preface
  • Acknowledgments
  • Authors
  • Introduction
  • Section I Pollutants and Their Fate in Ecosystems
  • 1. Major Classes of Pollutants
  • 1.1 Inorganic Ions
  • 1.1.1 Metals
  • 1.1.2 Anions
  • 1.2 Organic Pollutants
  • 1.2.1 Hydrocarbons
  • 1.2.2 Polychlorinated Biphenyls (PCBs)
  • 1.2.3 Polychlorinated Benzodioxins (PCDDs)
  • 1.2.4 Polychlorinated Dibenzofurans (PCDFs)
  • 1.2.5 Polybrominated Biphenyls (PBBs)
  • 1.2.6 Organochlorine Insecticides
  • 1.2.7 Organophosphorous Insecticides (OPs)
  • 1.2.8 Carbamate Insecticides
  • 1.2.9 Pyrethroid Insecticides
  • 1.2.10 Neonicotinoids
  • 1.2.11 Phenoxy Herbicides (Plant Growth Regulators)
  • 1.2.12 Anticoagulant Rodenticides
  • 1.2.13 Detergents
  • 1.2.14 Chlorophenols
  • 1.2.15 Ethinylestradiol (EE2)
  • 1.2.16 Pharmaceuticals
  • 1.3 Organometallic Compounds
  • 1.4 Radioactive Isotopes
  • 1.4.1 Introduction
  • 1.4.2 Natures and Intensities of Radioactive Decay Products
  • 1.4.3 Half-Lives
  • 1.4.4 Biochemistry
  • 1.5 Gaseous Pollutants
  • 1.6 Nanoparticles
  • 1.7 Summary
  • Further Reading
  • 2. Routes By Which Pollutants Enter Ecosystems
  • 2.1 Entry into Surface Waters
  • 2.2 Contamination of Land
  • 2.3 Discharge into Atmosphere
  • 2.4 Quantification of Release of Pollutants
  • 2.5 Summary
  • Further Reading
  • 3. Long-Range Movements and Global Transport of Pollutants
  • 3.1 Factors Determining Movements and Distributions of Pollutants.
  • 3.1.1 Polarity and Water Solubility
  • 3.1.2 Partition Coefficients
  • 3.1.3 Vapor Pressure
  • 3.1.4 Partition between Environmental Compartments
  • 3.1.5 Molecular Stability and Recalcitrant Molecules
  • 3.2 Transport in Water
  • 3.3 Transport in Air
  • 3.4 Models for Environmental Distribution of Chemicals
  • 3.5 Summary
  • Further Reading
  • 4. The Fate of Metals and Radioactive Isotopes in Contaminated Ecosystems
  • 4.1 Introduction
  • 4.1.1 Localization
  • 4.1.2 Persistence
  • 4.1.3 Bioconcentration and Bioaccumulation Factors
  • 4.1.4 Bioavailability
  • 4.1.5 Cocktails of Inorganic Pollutants
  • 4.2 Terrestrial Ecosystems
  • 4.2.1 Introduction
  • 4.2.2 Metals
  • 4.2.3 Radioactivity
  • 4.3 Aquatic Systems
  • 4.4 Summary
  • Further Reading
  • 5. Fates of Organic Pollutants in Individuals and in Ecosystems
  • 5.1 Fate within Individual Organisms
  • 5.1.1 General Model
  • 5.1.2 Processes of Uptake
  • 5.1.3 Processes of Distribution
  • 5.1.4 Storage
  • 5.1.5 Metabolism
  • 5.1.6 Sites of Excretion
  • 5.1.7 Toxicokinetic Models
  • 5.1.8 Toxicokinetic Models for Bioconcentration and Bioaccumulation
  • 5.2 Organic Pollutants in Terrestrial Ecosystems
  • 5.2.1 Fate in Soils
  • 5.2.2 Transfer along Terrestrial Food Chains
  • 5.3 Organic Pollutants in Aquatic Ecosystems
  • 5.3.1 Pollutants in Sediments
  • 5.3.2 Transfer along Aquatic Food Chains
  • 5.4 Summary
  • Further Reading
  • Section II Effects of Pollutants on Individual Organisms
  • 6. Testing for Ecotoxicity
  • 6.1 General Principles
  • 6.2 Determination of Toxicities of Mixtures
  • 6.3 Toxicity Testing with Terrestrial Organisms
  • 6.3.1 Introduction
  • 6.3.2 Invertebrate Testing
  • 6.3.2.1 Testing with Earthworms
  • 6.3.2.2 Tests with Springtails
  • 6.3.2.3 Tests with Beneficial Arthropods
  • 6.3.2.4 Automated Videotracking
  • 6.3.3 Vertebrates
  • 6.3.4 Plants
  • 6.4 Toxicity Testing with Aquatic Organisms
  • 6.4.1 Tests for Direct Absorption from Water
  • 6.4.2 Sediment Toxicity Tests
  • 6.5 Risk Assessment
  • 6.6 Field Testing for Toxicity
  • 6.7 Alternative Methods in Ecotoxicity Testing
  • 6.7.1 Alternative Methods for Estimating Toxicity to Vertebrates
  • 6.7.1.1 Toxicity Testing on Live Vertebrates
  • 6.7.1.2 Toxicity Testing on Nonvertebrates
  • 6.7.1.3 Toxicity Testing on Cellular Systems
  • 6.7.1.4 Predictive Models
  • 6.7.2 Alternative Approaches toward More Ecological End Points
  • 6.7.2.1 Field Studies
  • 6.7.2.2 Microcosms and Mesocosms
  • 6.7.2.3 Theoretical Models
  • 6.8 Summary
  • Further Reading
  • 7. Biochemical Effects of Pollutants
  • 7.1 Introduction
  • 7.2 Protective Biochemical Responses
  • 7.3 Molecular Mechanisms of Toxicity
  • 7.4 Examples of Molecular Mechanisms of Toxicity
  • 7.4.1 Genotoxic Compounds
  • 7.4.2 Neurotoxic Compounds
  • 7.4.3 Mitochondrial Poisons
  • 7.4.4 Vitamin K Antagonists
  • 7.4.5 Thyroxine Antagonists
  • 7.4.6 Inhibition of ATPases
  • 7.4.7 Environmental Estrogens and Androgens
  • 7.4.8 Reactions with Protein Sulfhydryl (SH) Groups
  • 7.4.9 Photosystems of Plants
  • 7.4.10 Plant Growth Regulator Herbicides
  • 7.5 Summary
  • Further Reading
  • 8. Physiological Effects of Pollutants
  • 8.1 Introduction
  • 8.2 Effects of Pollutants at Cellular Level
  • 8.3 Effects at Organ Level in Animals
  • 8.4 Effects at Whole Organism Level
  • 8.4.1 Neurophysiological Effects
  • 8.4.2 Effects on Behavior
  • 8.4.3 Reproductive Effects
  • 8.5 Effects on Plants
  • 8.6 Energy Costs of Physiological Change
  • 8.7 Summary
  • Further Reading
  • 9. Interactive Effects of Pollutants
  • 9.1 Introduction
  • 9.2 Additive Effects
  • 9.3 Potentiation of Toxicity
  • 9.4 Potentiation Due to Inhibition of Detoxification
  • 9.5 Potentiation from Increased Activation
  • 9.6 Field Detection of Potentiation
  • 9.7 Summary
  • Further Reading
  • 10. Biomarkers
  • 10.1 Classification of Biomarkers
  • 10.2 Specificity of Biomarkers
  • 10.3 Relationship of Biomarkers to Adverse Effects
  • 10.4 Specific Biomarkers
  • 10.4.1 Inhibition of Esterases
  • 10.4.2 The Induction of Monooxygenases
  • 10.4.3 Studies of Genetic Materials
  • 10.4.4 Porphyrins and Heme Synthesis
  • 10.4.5 Induction of Vitellogenin
  • 10.4.6 Behavioral Biomarkers
  • 10.4.7 Biomarkers in Plants
  • 10.5 Role of Biomarkers in Environmental Risk Assessment
  • 10.6 Summary
  • Further Reading
  • 11. In Situ Biological Monitoring
  • 11.1 Introduction
  • 11.2 Community Effects (Type 1 Biomonitoring)
  • 11.2.1 Terrestrial Ecosystems
  • 11.2.2 Freshwater Ecosystems
  • 11.2.3 Marine Ecosystems
  • 11.3 Bioconcentration of Pollutants (Type 2 Biomonitoring)
  • 11.3.1 Terrestrial Ecosystems
  • 11.3.2 Freshwater Ecosystems
  • 11.3.3 Marine Ecosystems
  • 11.4 Effects of Pollutants (Type 3 Biomonitoring)
  • 11.4.1 Terrestrial Ecosystems
  • 11.4.2 Freshwater Ecosystems
  • 11.4.3 Marine Ecosystems
  • 11.5 Genetically Based Resistance to Pollution (Type 4 Biomonitoring)
  • 11.6 Conclusions.
  • 11.7 Summary
  • Further Reading
  • Section III Effects of Pollutants on Populations and Communities
  • 12. Changes in Numbers: Population Dynamics
  • 12.1 Population Abundance
  • 12.2 Population Growth Rate
  • 12.3 Population Growth Rate Depends on the Properties of Individual Organisms
  • 12.3.1 The Life History and Population Growth Rate of the Coastal Copepod Eurytemora affinis
  • 12.4 Density Dependence
  • 12.5 Identifying Which Factors Are Density Dependent: k-Value Analysis
  • 12.6 Interactions between Species
  • 12.7 Field Studies: Three Case Studies
  • 12.7.1 The Decline of the Partridges
  • 12.7.2 Population Studies of Pesticides and Birds of Prey in the UK
  • 12.7.3 The Boxworth Project (Experimental Analysis of the Effects of Pesticides on Farmland)
  • 12.8 Modeling the Effects of Insecticides on Skylarks for Risk Assessment Purposes
  • 12.9 Summary
  • Further Reading
  • 13. Evolution of Resistance to Pollution
  • 13.1 Chronic Pollution Is Environmental Change
  • 13.2 Evolutionary Processes in Constant Environments
  • 13.3 The Evolution of Resistance When There Is a Mortality–Production Trade-Off
  • 13.4 Evolutionary Responses to Environmental Changes
  • 13.5 Monogenic Resistance
  • 13.6 Case Studies
  • 13.6.1 Evolution of Pesticide Resistance
  • 13.6.2 Evolution of Metal Tolerance in Plants
  • 13.6.3 Evolution of Industrial Melanism
  • 13.6.4 Evolutionary Response of Dog Whelks, Nucella lapillus, to TBT Contamination
  • 13.6.5 Evolution of Resistance to Pollution in Estuaries
  • 13.7 Summary
  • Further Reading
  • 14. Changes in Communities and Ecosystems
  • 14.1 Introduction
  • 14.2 Changes in Soil Processes: The Functional Approach
  • 14.3 Changes in Compositions of Communities: The Structural Approach
  • 14.3.1 Changes in Soil Ecosystems
  • 14.3.2 Acidification of Lakes and Rivers
  • 14.3.3 Mesocosms
  • 14.4 Global Processes
  • 14.5 Summary
  • Further Reading
  • 15. Extrapolating from Molecular Interactions to Consequent Effects at Population Level
  • 15.1 Introduction
  • 15.2 Translation of Toxic Effects across Organizational Boundaries
  • 15.2.1 From Effects at Site of Action to Localized Cellular Disturbances
  • 15.2.1.1 Example A: Action of Organophosphates on Acetylcholinesterase of Nervous System
  • 15.2.1.2 Example B: Action of p,p´-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes
  • 15.2.1.3 Example C: Action of p,p´-DDE on Transport of Calcium into Eggshell Glands of Birds
  • 15.2.1.4 Example D: Action of 17A-Ethinylestradiol (EE2) on Estrogenic Receptors of Fish
  • 15.2.2 From Cellular Disturbances to Effects at Whole Organism Level
  • 15.2.2.1 Example A: Actions of Organophosphates on Acetylcholinesterase of Nervous System
  • 15.2.2.2 Example B: Action of p,p´-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes
  • 15.2.2.3 Example C: Action of p,p´-DDE on Transport of Calcium into Eggshell Glands of Birds
  • 15.2.2.4 Example D: Action of 17A-Ethinylestradiol on Estrogenic Receptors of Fish
  • 15.2.3 From Effects on Whole Organism to Population Effects
  • 15.2.3.1 Example A: Actions of Organophosphates on Acetylcholinesterase of Nervous System
  • 15.2.3.2 Example B: Action of p,p´-DDT on Voltage-Dependent Sodium Channels of Axonal Membranes
  • 15.2.3.3 Example C: Action of p,p´-DDE on Transport of Calcium into Eggshell Glands
  • 15.2.3.4 Example D: Action of 17A-Ethinylestradiol on Estrogenic Receptors in Fish
  • 15.2.4 Complete Causal Chain
  • 15.3 Biomarker Strategies
  • 15.3.1 Establishing Causality Where Pollution Already Exists
  • 15.3.2 Biomarker Strategies in the Field
  • 15.3.3 Control Problems
  • 15.3.4 Selection of Biomarkers for Field Studies
  • 15.4 Biomarkers and Environmental Risk Assessment
  • 15.5 Summary
  • Further Reading
  • 16. Biomarkers in Population Studies
  • 16.1 DDE-Induced Eggshell Thinning in Raptorial and Fish-Eating Birds
  • 16.2 Reproductive Failure of Fish-Eating Birds on Great Lakes of North America
  • 16.3 Reproductive Failures of Mollusks Caused by Tributyl Tin
  • 16.4 Forest Spraying in Eastern Canada to Control Spruce Budworm
  • 16.5 Summary
  • Further Reading
  • 17. Ecotoxicology: Looking to the Future
  • 17.1 Changing Patterns of Chemical Pollution
  • 17.2 Environmental Risk Assessment
  • 17.3 The Use of Models in Population Risk Assessment
  • 17.4 Technological Advances and New Biomarker Assays
  • 17.5 A Better Integrated Approach to Environmental Risk Assessment?
  • 17.6 Ethical Issues
  • 17.7 Summary
  • Further Reading
  • Glossary
  • Bibliography
  • Index

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